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Cytochrome c folding pathway: Kinetic indigenous-condition hydrogen Trade PNAS September seventeen, 2002 Native-state hydrogen Trade experiments less than EX1 conditions can distinguish partly unfolded intermediates by their formation fees and establish the amide hydrogens uncovered and protected in Each and every.
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On the other hand, the nature of your contribution from small frequency procedures to drinking water leisure continues to be unclear. We have examined this issue by researching the drinking water T1ρ dispersion in peptide methods (14N- and 15N-labeled), glycosaminoglycan methods, and samples of bovine articular cartilage prior to and just after proteoglycan degradation. We find in model units and tissue that hydrogen Trade from NH and OH teams to h2o dominates the small frequency water T1ρ dispersion, within the context of the model utilized to interpret the relaxation data. Even more, reduced frequency dispersion variations are correlated with lack of proteoglycan from the additional-cellular matrix of articular cartilage. This finding has significance for your noninvasive detection of matrix degradation. Clearly show fewer See publication
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